Switching metal complexes<i>via</i>intramolecular electron transfer: connections with solvatochromism

Electron transfer between metal complexes: retrospective.

Electron transfer and catalysis with high-valent metal-oxo complexes.

High-valent metal-oxo complexes are produced by reductive activation of dioxygen via reduction of metal complexes with reductants and dioxygen. Photoinduced electron transfer from substrates to metal complexes with dioxygen also leads to the generation of high-valent metal-oxo complexes that can oxygenate substrates. In such a case metal complexes act as a photocatalyst to oxygenate substrates ...

Controlling the electron transfer mechanism in metal–molecules–metal junctions

We show how the mechanism of electron transfer through molecules can be switched between different regimes by using Hg-based metal–molecules–metal junctions. The junctions are easy to assemble and allow for hosting of self-assembled monolayers (SAMs) of a large variety of molecular structures. In this paper, we compare results from studies of charge transport across two different types of junct...

Photoinduced charge accumulation by metal ion-coupled electron transfer.

An oligotriarylamine (OTA) unit, a Ru(bpy)3(2+) photosensitizer moiety (Ru), and an anthraquinone (AQ) entity were combined to a molecular dyad (Ru-OTA) and a molecular triad (AQ-Ru-OTA). Pulsed laser excitation at 532 nm led to the formation of charge-separated states of the type Ru(-)-OTA(+) and AQ(-)-Ru-OTA(+) with lifetimes of ≤10 ns and 2.4 μs, respectively, in de-aerated CH3CN at 25 °C. U...

Ultrafast direct electron transfer at organic semiconductor and metal interfaces

The ability to control direct electron transfer can facilitate the development of new molecular electronics, light-harvesting materials, and photocatalysis. However, control of direct electron transfer has been rarely reported, and the molecular conformation-electron dynamics relationships remain unclear. We describe direct electron transfer at buried interfaces between an organic polymer semic...